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Modification of glassy carbon surfaces by atmospheric pressure cold plasma torch

机译:大气压冷等离子体炬对玻碳表面的改性

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摘要

The effect of plasma treatment on glassy carbon (GC) surfaces was studied with adhesion improvement in mind. A newly constructed remote plasma source was used to treat GC plates. Pure He and a dilute NH3/He mixture were used as feed gases. Optical emission spectroscopy was performed for plasma torch diagnostics. The treatment resulted in surface etching, substantially enhanced by NH3, as well as a roughening of the surface as measured by atomic force microscopy. Furthermore, the treated area showed an increased wettability indicating the addition of polar functional groups to the surface. X-ray photoelectron spectroscopy confirmed the introduction of several oxygen and nitrogen containing surface functional groups. The adhesion to epoxy was dramatically improved after exposure to either plasma, the effect being largest when NH3 was present in the feed gas.
机译:考虑到粘附力的提高,研究了等离子体处理对玻璃碳(GC)表面的影响。新建的远程等离子体源用于处理GC板。纯He和稀NH3 / He混合物用作进料气。进行了光谱发射光谱学诊断等离子炬。该处理导致表面蚀刻,其通过NH 3显着增强,以及通过原子力显微镜法测量的表面粗糙。此外,处理区域显示出增加的润湿性,表明在表面上增加了极性官能团。 X射线光电子能谱证实引入了几个含氧和氮的表面官能团。暴露于任何一种等离子体后,与环氧树脂的粘合力都得到了显着改善,当原料气中存在NH3时,效果最大。

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